Benzoic Acid vs Silicon Dioxide: which is worse?

What is Benzoic Acid?

Benzoic acid is a naturally occurring aromatic carboxylic acid found in cranberries, prunes, cinnamon, and many berries. It is used as a preservative against bacteria, yeast, and fungi at pH below 4.5. In the body, benzoic acid is conjugated with glycine to form hippuric acid, which is excreted in urine.

What is Silicon Dioxide?

Silicon dioxide (silica) is a naturally occurring mineral compound used as an anti-caking agent in powdered and granular foods. The food-grade form is amorphous (non-crystalline) synthetic silica, distinct from the crystalline quartz form associated with lung disease. It absorbs moisture and prevents clumping in powders.

Documented risks

Benzoic Acid: When benzoic acid (or sodium benzoate) is combined with ascorbic acid (vitamin C) in beverages, it can form benzene, a known carcinogen classified as Group 1 by IARC. This reaction is promoted by heat and light. The FDA and EFSA monitor benzene levels in beverages and have set informal guidance limits. A 1999 Lancet publication and the subsequent 2007 'Southampton study' did not directly involve benzoic acid, but sodium benzoate was included in the tested mixture. Some individuals with aspirin sensitivity may react to benzoic acid. The ADI is 5 mg/kg body weight/day.

Silicon Dioxide: Food-grade amorphous silicon dioxide is generally recognized as safe. EFSA re-evaluated it in 2018 and concluded there was no safety concern at typical dietary exposure levels; however, the panel noted uncertainty about nanoparticle forms. The food form should not be confused with crystalline silica (quartz) dust, which is a recognized carcinogen when inhaled occupationally. Ingested amorphous silica passes through the body largely unabsorbed.